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Mohit Pandey's Avatarhttp://hypography.com/forums/ Some basic concept problems
Mohit Pandey
Posted 10-19-2007
Please explain pointwise.
1.In the chemical changes which I have studied till now , precipitate appears and after adding more reactant, it dissolves. For example--
when ammonium hydroxide is added to copper sulphate solution, a blue precipitate appears. When more ammonium...
  #10  
By Mohit Pandey on 10-31-2007
Re: Some basic concept problems

Quote:
Originally Posted by modest View Post
Like I said before (and posted a link and method to prove this to yourself) you can't manufacture sulfuric acid by combining nitric acid and sulfur. If you believe otherwise - post a source.

-modest
1.Tutoring, Chemistry, Chemistry Tutoring, Group 16 (VIA) Elements-Oxygen and Sulphur, Sources of Oxygen, Sodium Peroxide, Rusting of Iron, Extraction of Sulphur, Potassium Chlorate, Frasch Process, Heat on Sulphur, Oxides - Tutorvista.com
2.Nitric acid Summary
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  #11  
By modest on 10-31-2007
Re: Some basic concept problems

It is true that concentrated nitric acid is a good oxidizer, but the result will be
sulfur dioxide, nitrogen monoxide and water vapor. I guess in a closed system the sulfur could be further oxidized - but the result would be a little bit of weak sulfuric acid in a large amount of concentrated nitric acid and nitrates. This is not an economic setup or result. All one has done here is to contaminate perfectly good concentrated nitric acid.
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  #12  
By Mohit Pandey on 10-31-2007
Smile Re: Some basic concept problems

#3 is clear. Move ahead.
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  #13  
By modest on 10-31-2007
Re: Some basic concept problems

Quote:
Originally Posted by Mohit Pandey View Post
4.
In my textbook it is written that
H2SO4 is a dibasic acid. It reacts with alkalis to form acid salts called hydrogensulphates and normal salts called sulphates.
Can anyone explain this? I have already Googled it without any satisfactory results.
Try to google bisulfate. That is the more common way of saying it. Basically (pun intended) - sulfate has a negative 2 charge and has no hydrogen. Hydrogen sulfate has a negative 1 charge and has a hydrogen.
Dibasic just means that there are 2 hydrogen ions in each molecule.

Quote:
Originally Posted by Mohit Pandey View Post
One more question.
NaOH + H2SO4(aq) ==NaHSO4(aq) + H2O
2NaOH + H2SO4(aq) == Na2SO4(aq) +H2O
Do these reactions occur at same time?
sodium sulfate and sodium bisulfate make an equilibrium in sulfuric acid.
the way to write it would be:



This is an example like your textbook says "It reacts with alkalis to form acid salts called hydrogensulphates and normal salts called sulphates"
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  #14  
By Mohit Pandey on 11-02-2007
Smile Re: Some basic concept problems

OK, everything cleared. Thank you Eric! and Modest!

My friends! if you have any doubts or views, post here.
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