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Originally Posted by Erasmus00
Why does fire have a well-defined outline?
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The glowing region of a flame does appear well-defined, particularly a small flame, such as that of a small brazing torch or a butane lighter adjusted to its lowest working setting.
Flame is plasma, atoms where the electrons have become disconnected from their nuclei. The glow is photons emitted by electrons as they become reconnected to nuclei in the plasma. Because electrons in plasma readily lose energy due to interaction with surrounding air (this is, of course, the source of the energy for convective heating), the plasma containing region is confined to an elongated spheroid region close to the combustion.
In a near vacuum, plasma loses far less energy to surrounding molecules, diffusing further and into more irregular shapes. Large fires involve stronger convective air currents, whipping the plasma envelopes into wilder shapes – in a large fire, such as a bonfire, small envelopes of plasma can be observed detaching from the main envelope and existing independently for very brief durations.