hi and welcome to this fora!
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If I have an n*m matrix X made up of n measurements of m variables (assuming all the variables measure temperature and so the units are Kelvin (K)). Does this imply that the covariance of X has units K^2?
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yes; just look at the definition of covariance, and you'll see that the elements occur squared.
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Also, if S = covariance(X) and S = ULU' (singular value decomposition), what are the units of U, L and U'??
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Since the matrices U and U' need to obey: U Ut = U't U' = 1, (t denotes the transposed matrix) they have to be unitless; So L has the same units as S.
Bo